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The rise of metals

Metal working is one of the Great Inventions of Mankind, like the wheel, writing and, to my biased mind, the harnessing of steam. 

The Copper age   The Bronze age   The Iron age

We’re talking work-a-day metals here.  To my mind, gold doesn’t count because it’s too easy.  Once you have found your nuggets of gold, all you have to do is to melt them, and pour them into a mould.  I’m sure that’s not quite fair, but the metals that actually transformed people’s lives are altogether more difficult.  Most metals are found in the form of ‘oxides’ (rust).  And they have to be ‘smelted’ using charcoal, to drag the oxygen off.  This is difficult, dangerous, and the fumes that arise are not at all good for you.

 

Pure metals tend to be too soft to be of any practical use.  It’s when you add a suitable leavening of other minerals (a few percent is enough) that they become hard enough and tough enough to make tools, weapons or anything else.  So don’t go asking for pure gold jewellery.  The stones would fall out, the fixings would break and you wouldn’t keep it long.  Much of the skill of the metal-master lies in removing unwanted impurities, and in introducing the right concentrations of the wanted ones. 

 

I’m finding it extremely difficult to give you any decent dates for the metals revolution.  This perhaps adds weight to the theory that it was ‘dark age’ peoples who had the freedom to innovate.  Once a civilisation was established, its elite saw change as a threat (more).

The Copper age

The first metal age was the copper age.  Copper oxide is green, so it’s easy to find.  Today’s architects sometimes sheath parts of their buildings in copper, and deliberately encourage it to ‘rust’ because they like the green colour.

 

The first smelters of copper seem to have been the Anatolians (Turks), 8 or 9 thousand years ago.  Slag heaps have been found in the weird ‘stone age’ settlement of Çatalhöyük, showing that they were already into copper smelting.  But this doesn’t seem to have been the start of any widespread copper age. 

 

A better age for the start of the copper age seems to be something over 5 thousand years ago.  You may remember Ötzi, the 5 thousand-year old mummified hunter who was found in the high Alps some years ago.  He carried a superb arsenical copper axe.  In fact I’ve read that he was actually a copper-master.  The argument is that he had so much arsenic and copper in his hair that he could have been nothing else.   I think (though I’m not sure) that arsenic tends to be found in copper deposits.   Even if it isn’t, adding arsenic to copper makes it strong and very tough.  So, one way or another any experienced copper-master would have been too well acquainted with arsenic for his own health.

The bronze age

The copper age doesn’t seem to have lasted very long though.  Indeed, not all authorities accept that there was a separate copper age at all.  Adding arsenic to copper may be good, but adding tin to it is very much better.  This produces bronze.  Some copper deposits have tin already mixed in with them, so when you smelt them you get bronze anyway. 

 

The bronze age seems to have started during the ‘dark’ age preceding the Sumerians, which is to say just over 5 thousand years ago.  It quickly spread around the Mediterranean, and to China.  But it didn’t reach Britain for another thousand years. 

 

The discovery of bronze was the real breakthrough, and it spawned a whole series of rich civilisations in the middle east and elsewhere (see previous link).

 

These days we use an improved version of bronze, adding zinc instead of tin, and call it brass.

The iron age

But bronze is not terribly strong, and it can’t take a truly hard edge for cutting.  So there was a need for a more durable metal still.  As far as I can gather the iron age began, again in the middle east, around 3 thousand years ago, and reached China 600 years later.   Apparently it didn’t reach Britain until some 2700 years ago.

 

I’ve read that it was not any of the great civilisations that discovered iron smelting either, but the Phoenicians, or possibly the Samaritans. 

 

Iron is funny stuff.  The main material you need to add to improve it is carbon – but only a few percent.  If you add just a little, you get wrought iron.  Wrought iron is a very useful material.  You can bend it and stretch it, but it is still pretty strong.  If you add a little more carbon, you get steel.  Steel is very hard and very strong.  And it’s the material that props up most of modern civilisation.  But if you add a little more carbon still, you don’t get better steel, you get cast iron.  Cast iron is quite strong.  The famous Iron Bridge is made of it.  But it’s brittle.  It won’t bend.  It breaks instead.

 

Perhaps we should end with a brief mention of ‘the steel age’.  Steel has been around since the middle ages.  The Indians were exporting quite a lot of it a thousand years ago.  But steelmaking was a cottage industry.  Steel was far too expensive to be used for much, except swords.   Only when Henry Bessemer invented his famous ‘converter’ (see previous link), around 200 years ago, did good steel become cheap enough to be widely used in industry. 

 

 © C B Pease, December 07